| 9. Functionalized Polymers 功能聚合物 _________________________________ | |
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| 9.1 Poly(meth)acrylate Based Functionalized Polymers | |
| | 9.1.1 Allyl Terminated Poly(isotactic methyl methacrylate) isocontents >92% 9.1.2 Amino Terminated Poly(methyl methacrylate)-isotactic rich (iso contents over 95%) 9.1.3 Amino Terminated Poly(methyl methacrylate)-Syndiotactic rich (>78%) (1) 9.1.4 Amino Terminated Poly(methyl methacrylate)-Syndiotactic rich (>78%), (2) 9.1.5 Amino Terminated Poly(propylacrylic acid) 9.1.6 Amino Terminated Poly(t-butyl methacrylate) 9.1.7 Bromo Terminated Poly(methyl methacrylate) 9.1.8 Carboxy Terminated Poly(isotactic methyl methacrylate)- Iso-contents over 92% 9.1.9 Carboxy Terminated Poly(methyl methacrylate)-syndiotactic contents over 78% 9.1.10 Carboxy Terminated Poly(n-butyl methacrylate) 9.1.11 Carboxy Terminated Poly(t-butyl acrylate) 9.1.12 Carboxy Terminated Poly(t-butyl methacrylate) 9.1.13 Carboxy Terminated Poly(neopentyl methacrylate) 9.1.14 Carboxy Terminated Poly(N,N-dimethylaminoethyl methacrylate) 9.1.15 Carboxy chloride Terminated Poly(methyl methacrylate) syndiotactic rich >80% 9.1.16 Hydroxy terminated Poly(ethyl acrylate) 9.1.17 Hydroxy Terminated Poly(methyl methacrylate), hydroxypropyl terminated 9.1.18 Hydroxy Terminated Poly(methyl methacrylate), hydroxyisopentyl terminated 9.1.19 Hydroxy terminated Poly(n-butyl acrylate), hydroxypropyl terminated 9.1.20 Hydroxy terminated Poly(n-butyl acrylate), hydroxy isopentyl terminated 9.1.21 Hydroxy Terminated Poly(methyl methacrylate), diphenylmethyl-ol 9.1.22 Hydroxy Terminated Poly(neopentyl methacrylate) 9.1.23 Hydroxy Terminated Poly(t-butyl methacrylate) 9.1.24 Olefinic Vinyl Terminated Poly(methyl methacrylate) syndiotactic rich > 80% 9.1.25 Vinyl Terminated Poly(methyl methacrylate) Syndiotactic >80% 9.1.26 Vinyl Terminated Poly(t-butyl acrylate) 9.1.27 α ω-Diamino Terminated Poly(methyl methacrylate) 9.1.28 α ω-Dicarboxy Terminated Poly(methyl methacrylate) 9.1.29 α,ω-Dicarboxy Terminated Poly(t-butyl acrylate) 9.1.30 α-Amino ω-Thiol Terminated Poly(t-butyl methacrylate) 9.1.31 α-Amino End Protected Poly(t-butyl methacrylate) 9.1.32 Amino End Protected Poly(methyl methacrylate) 9.1.33 Poly(methyl methacrylate) macromonomer (vinyl) 9.1.34 α-Amino End Protected and ω-Thiol Terminated Poly(methyl methacrylate) 9.1.35 α-Amino End Protected and ω-Thiol Terminated Poly(t-butyl methacrylate) 9.1.36 α-Hydroxy-ω-Carboxyl Terminated Poly(methyl methacrylate) 9.1.37 α-Hydroxy-ω-Bromo Terminated Poly(methyl methacrylate) Syndiotactic rich 9.1.38 α-Hydroxy-ω-Bromo Terminated Poly(methyl methacrylate-ester linkage) Hetrotactic rich Microstructure | |
| 9.2 Polyacrylamide Based Functionalized Polymers | |
| | 9.2.1 Amino Terminated Poly(N-isopropyl acrylamide) 9.2.2 Carboxy Terminated Poly(N-isopropyl acrylamide) 9.2.3 Hydroxy Terminated Poly(N-isopropyl acrylamide) 9.2.4 NHS terminated Poly(N-isopropyl acrylamide) 9.2.5 Thiol terminated Poly(N-isopropyl acrylamide) 9.2.6 α,ω-dicarboxy terminated poly(N-isopropyl acrylamide 9.2.7 α-carboxy ω-hydroxy terminated N-isopropyl acrylamide 9.2.8 α-carboxy ω-thiol terminated poly(N-isopropyl acrylamide | |
| 9.3 Polyisobutylene Based Functionalized Polymers | |
| | 9.3.1 Olefinic Vinyl Terminated Polyisobutylene 9.3.2 α,ω-Dihydroxy Terminated Polyisobutylene 9.3.3 α,ω-Divinyl Terminated Polyisobutylene | |
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| 9.7 Poly(propylene glycol) Based Functionalized Polymers | |
| | 9.7.1 α,ω-Diamino Terminated Poly(propylene glycol) 9.7.2 α-Bromo-ω-Hydroxy Terminated Poly(propylene glycol) | |
| 9.8 Poly(9,9-di-n-hexyl-2,7-fluorene) Based Functionalized Polymers | |
| | 9.8.1 Bromo-Terminated Prepolymer (Macroinitiator for ATRP) 9.8.2 Hydroxy-Terminated Prepolymer (Macroinitiator for Ring-Opening Polymerization) | |
| 9.9 Poly Lactone (Lactide) Based Functionalized Polymers | |
| | 9.9.1 Acryl terminated poly(ε-caprolactone) 9.9.2 Allyloxyethyl terminated poly(ε-caprolactone) 9.9.3 Dibromo terminated polylactide 9.9.4 Dibromo terminated poly(ε-caprolactone) 9.9.5 Lithocholic acid functionalized Poly Lactide 9.9.6 Lithocholic methyl ester end functionalized Poly Lactide 9.9.7 Dicarboxy terminated poly(ε-caprolactone) 9.9.8 α, ω-Dicarboxyl Terminated Poly(D/L-lactide) 9.9.9 Thiol terminated poly(ε-caprolactone) | |
| 9.10 Polystyrene Based Functionalized Polymer | |
| | 9.10.1 Amino Terminated Polystyrene (no silane or amide linkage) 9.10.2 Amino Terminated Polystyrene (amide linkage) 9.10.3 Amino Terminated Polystyrene (silane linkage) 9.10.4 Amino End Protected Polystyrene 9.10.5 Carboxy Terminated Polystyrene 9.10.6 Carboxy Terminated Polystyrene Cesium Salt 9.10.7 Carboxy Terminated Poly(4-t-butyl styrene) 9.10.8 Carboxyl Chloride Terminated Polystyrene 9.10.9 Dimethyl Chlorosilane Terminated Polystyrene 9.10.10 Dimethyl Silane Terminated Polystyrene 9.10.11 Ferrocenyldimethylsilane Terminated Polystyrene 9.10.12 Hydroxy Terminated Polystyrene 9.10.13 Hydroxy Terminated Poly(4-t-butyl styrene) 9.10.14 Hydroxy Terminated Polystyrene, diphenylmethyl-ol 9.10.15 Sulfonic Acid Terminated Polystyrene 9.10.16 Sulfonic Acid Sodium Salt Terminated Polystyrene 9.10.17 Thiol Terminated Polystyrene (1) 9.10.18 Thiol Terminated Polystyrene (2) 9.10.19 Vinyl Terminated Polystyrene 9.10.20 1,1-Diphenyl Ethylene Terminated Polystyrene 9.10.21 1,2-Dicarboxyethyl Terminated Polystyrene 9.10.22 α,α-Dihydroxy Terminated Polystyrene (silane bridge) 9.10.23 α,ω-Dicarboxy Terminated Polystyrene 9.10.24 α,ω-Dihydroxy Terminated Polystyrene 9.10.25 α,ω-Disulfonic Acid Terminated Polystyrene 9.10.26 α,ω-Hydroxy Terminated Polystyrene Bearing C=O in the Center* 9.10.27 α-Amino ω-Thiol terminated Polystyrene 9.10.28 α-hydroxy, ω-carboxy terminated Polystyrene 9.10.29 α-Hydroxyl-ω-Tempo moiety Terminated Poly(4-acetoxystyrene) 9.10.30 α-Hydroxyl-ω-Bromide moiety Terminated Poly(methacrylate-co-styrene) | |
| 9.11 Polysiloxane Based Functionalized Polymers | |
| | 9.11.1 Amino Terminated Polydimethylsiloxane 9.11.2 Bromo Terminated Polydimethylsiloxane 9.11.3 Carboxy Terminated Polydimethylsiloxane (1) Monofunctional 9.11.4 Carboxy Terminated Polydimethylsiloxane (2) Monofunctional 9.11.5 Chloro Terminated Polydimethylsiloxane- Monofunctional 9.11.6 Cyano Terminated Polydimethylsiloxane-Monofunctional 9.11.7 Dansyl amide terminated Polydimethylsiloxane (1) 9.11.8 Dansyl amide terminated Polydimethylsiloxane (2) 9.11.9 Dimethyl Chlorosilane Terminated Polydimethylsiloxane-Monofunctional 9.11.10 Dimethylsilane Terminated Polydimethylsiloxane-Monofunctional 9.11.11 Hydroxy (carbinol)Terminated Polydimethylsiloxane-Monofunctional 9.11.12 Methacrylate Terminated Polydimethylsiloxane-Monofunctional 9.11.13 Glycidyl terminated Polydimethylsiloxane-Monofunctional 9.11.14 α,ω-Benzyl chloride Terminated Polydimethylsiloxane 9.11.15 α,ω-Diacryloxy Terminated Polydimethylsiloxane 9.11.16 α,ω-Diallyl Terminated Polydimethylsiloxane 9.11.17 α,ω-Diamino Terminated Polydimethylsiloxane 9.11.18 α,ω-Dicarboxy Terminated Polydimethylsiloxane 9.11.19 α,ω-Dihydroxy Terminated Polydimethylsiloxane 9.11.20 α,ω-Disilane terminated Polydimethylsiloxane | |
| 9.12 Poly(vinyl pyridine) Based Functionalized Polymers | |
| | 9.12.1 Amino Terminated Poly(2-vinyl pyridine) 9.12.2 Carboxy Terminated Poly(2-vinyl pyridine) 9.12.3 Carboxy Terminated Poly(vinyl imidazole) 9.12.4 Hydroxy Terminated Poly(2-vinyl pyridine) 9.12.5 Hydroxy Terminated Poly(4-vinyl pyridine) 9.12.6 Thiol Terminated Poly(2-vinyl pyridine) 9.12.7 Thiol Terminated Poly(4-vinyl pyridine) 9.12.8 Vinyl Terminated Poly(4-vinyl pyridine) 9.12.9 α,ω-Dihydroxy Terminated Poly(2-vinyl pyridine) 9.12.10 α-Amino, ω-Carboxy Terminated Poly(2-vinyl pyridine) | |
| 9.13 Poly(vinylpyrrolidone) Based Functionalized Polymers | |
| | 9.13.1 Carboxy Terminated Poly(vinyl pyrrolidone) 9.13.2 Hydroxy Terminated Poly(vinyl pyrrolidone) 9.13.3 Thiol terminated poly(vinyl pyrrolidone) 9.13.4 α,ω-Dicarboxy Terminated Poly(vinyl pyrrolidone) | |
| 9.14 Funtionalized Diblock and TriBlock Copolymers | |
| | 9.14.1 ω-Amino Terminated Poly(butadiene-b-ethylene oxide) 9.14.2 ω-Carboxy Terminated Poly(butadiene-b-ethylene oxide) 9.14.3 Succinic acid Terminated Poly(butadiene-b-ethylene oxide) diblock copolymer 9.14.4 4-Methoxy benzyolester Terminated Poly(butadiene-b-ethylene oxide) diblock copolymer 9.14.5 Amino Terminated Poly(ethylene oxide-b-lactide) 9.14.6 Amino Terminated Poly(dimethylsiloxane-b-diphenylsiloxane) 9.14.7 Formyl Terminated Poly(ethylene oxide-b-lactide (DL)) 9.14.8 α-Amino-ω-Hydroxy Terminated Poly(ethylene glycol-b-ε-caprolactone) 9.14.9 α-Amino Terminated Poly(ethylene glycol-b-methacrylic acid) 9.14.10 α-Protected Amino Terminated Poly(ethylene glycol-b-t-butyl methacrylate) 9.14.11 α-Tetrahydropyranyl Terminated Poly(ethylene glycol-b-t-butyl methacrylate) 9.14.12 α-t-butoxycarbonylamino (BOC) Terminated Poly(ethylene glycol-b-t-butyl methacrylate) 9.14.13 α,ω-Disuccinimidyl Succinate Terminated Poly(ethylene oxide-propylene oxide-ethylene oxide) 9.14.14 Hydroxy Terminated Poly(methyl methacrylate-b-styrene) with Bromide terminal end towards polystyrene block 9.14.15 α-Hydroxy Terminated Poly(styrene-b-butadiene(1,2-addition)) 9.14.16 Amino Terminated Poly(styrene-b-isoprene) 9.14.17 Cabinol at the junction of Poly(styrene-b-isoprene(1,4 addition)) 9.14.18 α-Amino Terminated Poly(styrene-b-ethylene oxide) with hydroxy at the junction 9.14.19 Hydroxy at the junction of Poly(styrene-b-ethylene oxide) 9.14.20 ω-Carboxy Terminated Poly(styrene-b-ethylene oxide) 9.14.21 Hydroxy Terminated Poly(styrene-b-methyl methacrylate) 9.14.22 Hydroxy at the junction of Poly(styrene-b-2-vinyl pyridine) 9.14.23 Hydroxy Terminated Poly(styrene-b-2-vinyl pyridine) 9.14.24 Silane at the junction of Poly(styrene-b-2-vinyl pyridine) 9.14.25 α-Amino Terminated Poly(2-vinyl pyridine-b-ethylene oxide) with hydroxy at the junction 9.14.26 Hydroxy Terminated Poly(methyl methacrylate-b-styrene) with Bromide terminal end towards polystyrene block (PMMA>78% syndiotacticity) | |
| 9.15 Funtionalized Random and Alternating Copolymers | |
| | 9.15.1 Random Copolymer Poly(methyl methacrylate-co-styrene) α-Hydroxyl-ω-Bromide moiety Terminated 9.15.2 Random Copolymer Poly(styrene-co-methyl methacrylate) α-Hydroxyl-ω-Tempo moiety Terminated 9.15.3 Random Copolymer Poly(styrene-co-PEO methacrylate) α-Hydroxyl-ω-Tempo moiety Terminated | |